Evaluation and Comparison of Novel, Low-cost Sorbents for Mercury Control

نویسندگان

  • Trevor Ley
  • Rick Slye
چکیده

The injection of sorbents upstream of a particulate control device is one of the most promising methods for controlling mercury emissions from coal-fired utility boilers with electrostatic precipitators and fabric filters. Studies carried out at the bench-, pilot-, and fullscale have shown that a wide variety of factors may influence the mercury removal effectiveness. These factors include mercury species, flue gas composition, process conditions, existing pollution control equipment design, and sorbent characteristics. The objective of the program is to obtain the necessary information to assess the viability of lower cost alternatives to commercially available activated carbon for mercury control in coal-fired utilities. Prior to injection testing, a number of sorbents were tested in a slipstream fixed-bed device both in the laboratory and at two field sites. Based upon the performance of the sorbents in a fixed-bed device and the estimated cost of mercury control using each sorbent, seventeen sorbents were chosen for screening in a slipstream injection system at a site burning a bituminous coal/petcoke blend and five were chosen for screening at a site burning PRB coal. Evaluated sorbents were derived from various materials, which include: activated carbon samples from coal, biomass and tires; char sorbents made from coal; flyash derived sorbents; and zeolite-based sorbents. The economics and performance of the novel sorbents evaluated demonstrate that there are alternatives to the commercial standard. Smaller enterprises may have the opportunity to provide a lower price to their customers under the right set of circumstances.

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تاریخ انتشار 2003